NiO-Ni-Al2O3(γ) Nanocatalyst by Pulse Electrocodeposition Over Ni Open-cell Foam for Methane Reforming
نویسندگان
چکیده
Global warming persuades researchers to improve the effectiveness of renewable energy technologies, such as H2 production by methane steam reforming (MSR) an endothermic process. Herein, a nanocatalyst based on open-cell nickel foam 40 (pore per inch) with high thermal conductivity was prepared. The synthesized chemical stepwise synthesis approach, pre-treatment, pulsed electrocodeposition Ni-Al2O3(γ) nanoparticles, and calcination. Measurements diffusivity(α) flash xenon technique gained 4.41×10-6 m2s-1 values specific heat capacity, Cp, differential scanning calorimetry (DSC) conductivity(λ) enhanced 65% in temperature range 150 550°C Ni-alumina(γ) nanocatalyst. Furthermore, characterization tests for comparing indicated that hardness improved from 145 Vickers (HV) 547 HV compression strength increased 1.1 MPa 5MPa surface area (SBET) 1.48 m2g-1 48 m2g-1. XRD (x-ray diffraction) analysis showed NiO NiAl2O4 structure. interface between catalytic component (NiAl2O4), affected ability MSR, efficiency at low tempreture 500 °C same reported 720°C other investigations.
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ژورنال
عنوان ژورنال: International journal of engineering. Transactions A: basics
سال: 2023
ISSN: ['1728-1431']
DOI: https://doi.org/10.5829/ije.2023.36.10a.15